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A Level H2 Physics Modern Physics Quiz
Free A Level H2 Physics Modern Physics quiz, LongCat Exam version, with questions, answers, and A Level-style practice for Singapore students.
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Questions
A-Level Physics H2 Quiz - Modern Physics
Name: ____________________
Class: ____________________
Date: ____________________
Score: ______ / 60
Duration: 75 minutes
Total Marks: 60
Instructions:
- Answer ALL questions.
- Write your answers in the spaces provided.
- Show all working clearly for calculation questions. Marks are awarded for correct method even if the final answer is incorrect.
- The number of marks for each question or part-question is shown in brackets [ ].
- You may use a calculator.
- Fundamental constants are provided where needed.
Useful Constants:
- Speed of light in vacuum: c=3.00×108 m s−1
- Planck's constant: h=6.63×10−34 J s
- Elementary charge: e=1.60×10−19 C
- Electron mass: me=9.11×10−31 kg
- Avogadro's number: NA=6.02×1023 mol−1
- Unified atomic mass unit: 1 u=1.66×10−27 kg
Section A: Short Answer Questions (Questions 1–10)
Answer ALL questions. Each question carries 2 or 3 marks.
1. State what is meant by the photoelectric effect. [2]
2. A metal surface has a work function of 3.5 eV. Calculate the threshold frequency for this metal. [2]
3. Monochromatic light of wavelength 450 nm is incident on a metal surface with work function 2.3 eV.
(a) Calculate the energy of a single photon of this light, in eV. [2]
(b) Determine the maximum kinetic energy of the emitted photoelectrons, in eV. [1]
4. Explain why the photoelectric effect cannot be explained by the wave theory of light. Your answer should refer to at least two observations that contradict wave theory predictions. [3]
5. The de Broglie wavelength of an electron is 1.5×10−10 m. Calculate the speed of the electron. [3]
6. State what is meant by nuclear binding energy. [2]
7. A nucleus of uranium-235 (92235U) undergoes fission when it absorbs a neutron. One possible reaction is:
92235U+01n→54140Xe+3894Sr+201n
State and explain whether energy is released or absorbed in this reaction, given the following data:
- Mass of 92235U=235.0439 u
- Mass of 54140Xe=139.9216 u
- Mass of 3894Sr=93.9154 u
- Mass of 01n=1.0087 u [3]
8. A radioactive sample has an initial activity of 800 Bq. After 30 minutes, the activity has fallen to 100 Bq.
(a) Determine the half-life of the sample. [2]
(b) What will the activity be after a further 30 minutes? [1]
9. The energy levels of a hydrogen atom are shown below.

Generated diagram for Q9.
(a) Calculate the frequency of the photon emitted in Transition A. [2]
(b) Determine which transition, A or B, produces a photon with a longer wavelength. Explain your reasoning. [1]
10. Explain what is meant by wave-particle duality, giving one example of each: a phenomenon demonstrating the wave nature of matter, and a phenomenon demonstrating the particle nature of light. [3]
Section B: Structured Questions (Questions 11–17)
Answer ALL questions. Each question carries 5 or 6 marks.
11. In a photoelectric experiment, light of different frequencies is incident on a clean metal surface. The maximum kinetic energy Ek of the emitted photoelectrons is measured for each frequency f. The results are plotted on the graph below.

Generated graph for Q11.
(a) Using the graph, determine the threshold frequency of the metal. [1]
(b) Use your answer in (a) and the graph to determine Planck's constant. Show your working clearly. [3]
(c) Determine the work function of the metal in joules. [1]
12. An electron is accelerated from rest through a potential difference of 120 V.
(a) Calculate the kinetic energy gained by the electron, in joules. [2]
(b) Calculate the speed of the electron after being accelerated. [2]
(c) Calculate the de Broglie wavelength of this electron. [2]
13. The radioactive decay law is given by:
A=A0e−λt
where A is the activity at time t, A0 is the initial activity, and λ is the decay constant.
(a) Show that the half-life t1/2 is related to the decay constant λ by the expression:
t1/2=λln2
[2]
(b) A sample of a radioactive isotope has a half-life of 8.0 days. Calculate the decay constant λ in s−1. [2]
(c) If the initial number of nuclei in the sample is 2.0×1015, calculate the initial activity in Bq. [2]
14. Cobalt-60 (2760Co) is a radioactive isotope used in medical treatments. It decays by beta-minus decay.
(a) Write a nuclear equation for the decay of cobalt-60. [2]
(b) The decay constant of cobalt-60 is 4.17×10−9 s−1. Calculate the half-life of cobalt-60 in years. [3]
(c) Explain why the activity of a radioactive sample decreases over time, referring to the number of undecayed nuclei. [1]
15. A beam of X-rays of wavelength 0.071 nm is directed at a crystal. The first-order diffraction maximum is observed at a glancing angle of 12.5°.

Generated experimental_setup for Q15.
(a) State Bragg's law. [1]
(b) Calculate the spacing d between the crystal planes. [2]
(c) Explain why X-rays are used rather than visible light for crystal diffraction experiments. [2]
16. The following data relates to the isotope iron-56 (2656Fe):
- Mass of 2656Fe nucleus =55.9349 u
- Mass of proton =1.0073 u
- Mass of neutron =1.0087 u
(a) Calculate the mass defect of the iron-56 nucleus. [2]
(b) Calculate the binding energy of the iron-56 nucleus in MeV. [2]
(c) Calculate the binding energy per nucleon for iron-56. [1]
(d) On the axes below, sketch a graph of binding energy per nucleon against nucleon number, showing the general trend. Indicate the approximate position of iron-56 on your graph.

Generated graph for Q16.
[1]
17. A laser produces light of wavelength 632 nm with a power output of 2.0 mW.
(a) Calculate the energy of a single photon emitted by this laser. [2]
(b) Calculate the number of photons emitted per second. [2]
(c) Explain what is meant by stimulated emission and why it is essential for laser action. [2]
Section C: Data Interpretation and Application (Questions 18–20)
Answer ALL questions. Each question carries 6 or 7 marks.
18. A student carries out a photoelectric experiment using a photocell. Light of different wavelengths is directed at the cathode, and the stopping potential Vs is measured for each wavelength. The results are shown in the table below.
| Wavelength / nm | Stopping potential Vs / V |
|---|---|
| 580 | 0.35 |
| 520 | 0.62 |
| 460 | 0.95 |
| 400 | 1.32 |
| 340 | 1.78 |
(a) Using the data, plot a graph of stopping potential Vs against frequency f on the grid below.

Generated graph for Q18.
[3]
(b) From your graph, determine: (i) the threshold frequency, [1]
(ii) the work function of the cathode material in eV. [1]
(c) The student repeats the experiment with a different cathode material and finds that the gradient of the Vs vs f graph is the same but the threshold frequency is higher. Explain what this tells us about the new cathode material. [1]
19. Nuclear fusion is the process that powers the Sun. One important fusion reaction is:
12H+13H→24He+01n
where 12H is deuterium and 13H is tritium.
The masses are:
- 12H=2.0141 u
- 13H=3.0160 u
- 24He=4.0026 u
- 01n=1.0087 u
(a) Show that the mass defect for this reaction is 0.0188 u. [1]
(b) Calculate the energy released in this fusion reaction in MeV. [2]
(c) Calculate the binding energy per nucleon for tritium (13H), given that its mass is 3.0160 u. [3]
(d) Explain why fusion reactions release energy, making reference to the binding energy per nucleon curve. [1]
20. The following passage describes the operation of a scanning tunnelling microscope (STM).
A scanning tunnelling microscope uses the quantum mechanical phenomenon of electron tunnelling to image surfaces at the atomic level. A very sharp conducting tip is brought extremely close to the surface of a conducting sample (within about 1 nm). When a potential difference is applied between the tip and the sample, electrons tunnel through the vacuum gap, producing a tunnelling current. This current is exponentially sensitive to the width of the gap — a change in gap distance of just 0.1 nm changes the current by approximately one order of magnitude. The tip is scanned across the surface, and a feedback loop adjusts the tip height to maintain a constant tunnelling current. The record of tip height variations produces an atomic-resolution image of the surface.
(a) Explain what is meant by quantum tunnelling. [2]
(b) The tunnelling current I varies approximately as:
I∝e−2κd
where d is the gap width and κ is a constant that depends on the work function of the material. If the gap width increases from 0.50 nm to 0.62 nm, and κ=1.0×1010 m−1, calculate the ratio of the final current to the initial current. [3]
(c) Explain why the STM can achieve atomic resolution, making reference to the exponential relationship between current and gap width. [2]
END OF QUIZ
Answers
A-Level Physics H2 Quiz - Modern Physics
Answer Key and Marking Scheme
Section A: Short Answer Questions (Questions 1–10)
1. State what is meant by the photoelectric effect. [2]
Answer: The photoelectric effect is the emission of electrons from the surface of a metal when electromagnetic radiation (light) of sufficiently high frequency is incident on it.
Marking:
- [1] for mentioning emission of electrons from a metal surface
- [1] for mentioning that electromagnetic radiation/light of sufficiently high frequency is required
Teaching notes: The key idea is that light can knock electrons out of a metal, but only if the light frequency exceeds a certain threshold. This is a quantum phenomenon — the energy comes in discrete packets (photons), not as a continuous wave.
2. A metal surface has a work function of 3.5 eV. Calculate the threshold frequency for this metal. [2]
Answer: At the threshold frequency, the photon energy equals the work function:
hf0=ϕ
f0=hϕ=6.63×10−343.5×1.60×10−19
f0=6.63×10−345.60×10−19=8.45×1014 Hz
Marking:
- [1] for correct formula f0=ϕ/h with correct conversion of eV to J (3.5×1.60×10−19)
- [1] for correct final answer 8.45×1014 Hz (accept 8.4 to 8.5×1014)
Common mistake: Forgetting to convert eV to joules before dividing by h.
3. Monochromatic light of wavelength 450 nm is incident on a metal surface with work function 2.3 eV.
(a) Calculate the energy of a single photon of this light, in eV. [2]
Answer: E=λhc=450×10−96.63×10−34×3.00×108=4.42×10−19 J
Converting to eV:
E=1.60×10−194.42×10−19=2.76 eV
Marking:
- [1] for correct substitution into E=hc/λ
- [1] for correct answer 2.76 eV (accept 2.7 to 2.8)
(b) Determine the maximum kinetic energy of the emitted photoelectrons, in eV. [1]
Answer: Using Einstein's photoelectric equation:
Ek=hf−ϕ=2.76−2.3=0.46 eV
Marking:
- [1] for correct answer 0.46 eV
Teaching notes: Einstein's photoelectric equation states that the maximum kinetic energy of photoelectrons equals the photon energy minus the work function. The work function is the minimum energy needed to liberate an electron from the metal surface.
4. Explain why the photoelectric effect cannot be explained by the wave theory of light. Your answer should refer to at least two observations that contradict wave theory predictions. [3]
Answer: Wave theory predicts that:
- Electrons should be emitted for any frequency of light, given sufficient intensity, because energy accumulates continuously. However, there is a threshold frequency below which no electrons are emitted regardless of intensity. [1]
- Wave theory predicts a time delay between illumination and emission as electrons accumulate energy, but photoelectrons are emitted almost instantaneously. [1]
- Wave theory predicts that increasing intensity should increase the kinetic energy of emitted electrons, but increasing intensity only increases the number of photoelectrons; the maximum kinetic energy depends only on frequency. [1]
Marking: Award [1] each for any three valid contradictions. Minimum two required for full marks; third serves as a bonus point.
Teaching notes: This question tests understanding of why the photoelectric effect was pivotal in establishing quantum theory. The wave theory fails on multiple counts, and Einstein's photon model resolves all the contradictions.
5. The de Broglie wavelength of an electron is 1.5×10−10 m. Calculate the speed of the electron. [3]
Answer: Using the de Broglie relation:
λ=mvh
v=meλh=9.11×10−31×1.5×10−106.63×10−34
v=1.3665×10−406.63×10−34=4.85×106 m s−1
Marking:
- [1] for correct formula λ=h/(mv) rearranged for v
- [1] for correct substitution of values
- [1] for correct answer 4.85×106 m s−1 (accept 4.8 to 4.9×106)
Teaching notes: De Broglie proposed that all matter has wave-like properties. The wavelength is inversely proportional to momentum. This is a fundamental concept in quantum mechanics and is demonstrated experimentally by electron diffraction.
6. State what is meant by nuclear binding energy. [2]
Answer: Nuclear binding energy is the energy required to completely separate all the nucleons (protons and neutrons) in a nucleus. Equivalently, it is the energy released when nucleons combine to form the nucleus.
Marking:
- [1] for stating it is the energy required to separate all nucleons in a nucleus
- [1] for stating equivalently that it is the energy released when the nucleus is formed from its constituent nucleons
Teaching notes: The binding energy arises from the mass defect — the nucleus has less mass than the sum of its individual nucleons. The "missing" mass has been converted to energy via E=mc2, which holds the nucleus together.
7. State and explain whether energy is released or absorbed in this fission reaction. [3]
Answer: Calculate total mass before: mbefore=235.0439+1.0087=236.0526 u
Calculate total mass after: mafter=139.9216+93.9154+2(1.0087)=139.9216+93.9154+2.0174=235.8544 u
Mass defect: Δm=236.0526−235.8544=0.1982 u
Since the total mass after the reaction is less than the total mass before, mass has been lost. [1] This mass defect is converted to energy according to E=Δmc2. [1] Therefore, energy is released in this reaction. [1]
Marking:
- [1] for correct calculation showing mass after < mass before
- [1] for stating that the mass defect is converted to energy via E=Δmc2
- [1] for concluding that energy is released
Teaching notes: In nuclear reactions, if the products have less mass than the reactants, the "missing" mass has been converted to kinetic energy of the products. This is the principle behind nuclear power and nuclear weapons.
8. A radioactive sample has an initial activity of 800 Bq. After 30 minutes, the activity has fallen to 100 Bq.
(a) Determine the half-life of the sample. [2]
Answer: The activity drops from 800 → 400 → 200 → 100 Bq, which is 3 half-lives.
3×t1/2=30 minutes
t1/2=10 minutes
Marking:
- [1] for identifying that 3 half-lives have elapsed (800→400→200→100)
- [1] for correct answer: 10 minutes
(b) What will the activity be after a further 30 minutes? [1]
Answer: A further 30 minutes = 3 more half-lives: 100→50→25→12.5 Bq
Activity = 12.5 Bq
Marking:
- [1] for correct answer 12.5 Bq
9. Energy level diagram for hydrogen.
(a) Calculate the frequency of the photon emitted in Transition A (n=3→n=1). [2]
Answer: Energy of photon: ΔE=E3−E1=(−1.51)−(−13.6)=12.09 eV
Converting to joules: ΔE=12.09×1.60×10−19=1.934×10−18 J
Frequency: f=hΔE=6.63×10−341.934×10−18=2.92×1015 Hz
Marking:
- [1] for correct energy difference calculation (12.09 eV or 1.934×10−18 J)
- [1] for correct frequency 2.92×1015 Hz
(b) Determine which transition, A or B, produces a photon with a longer wavelength. Explain your reasoning. [1]
Answer: Transition B (n=4→n=2) produces a photon with a longer wavelength. The energy difference for Transition B is E4−E2=(−0.85)−(−3.40)=2.55 eV, which is smaller than Transition A's 12.09 eV. Since E=hf=hc/λ, a smaller energy means a lower frequency and therefore a longer wavelength.
Marking:
- [1] for correct answer (Transition B) with valid reasoning linking smaller energy to longer wavelength
Teaching notes: The energy level diagram shows that transitions between lower energy levels release more energetic photons (shorter wavelength). The Balmer series (n→2) produces visible light, while the Lyman series (n→1) produces ultraviolet.
10. Explain what is meant by wave-particle duality, giving one example of each. [3]
Answer: Wave-particle duality is the concept that all matter and radiation exhibit both wave-like and particle-like properties depending on the experiment being performed. [1]
- Wave nature of matter: Electron diffraction — a beam of electrons passing through a thin crystal produces a diffraction pattern, which is a wave phenomenon. [1]
- Particle nature of light: The photoelectric effect — light behaves as discrete packets of energy (photons), each carrying energy E=hf, which explains the threshold frequency and instantaneous emission. [1]
Marking:
- [1] for definition of wave-particle duality
- [1] for a valid example of wave nature of matter
- [1] for a valid example of particle nature of light
Section B: Structured Questions (Questions 11–17)
11. Photoelectric effect graph of Ek vs f.
(a) Using the graph, determine the threshold frequency of the metal. [1]
Answer: The threshold frequency is where the line intercepts the frequency axis (Ek=0). From the graph, f0=6.0×1014 Hz.
Marking:
- [1] for reading f0=6.0×1014 Hz from the graph
(b) Use your answer in (a) and the graph to determine Planck's constant. [3]
Answer: Using Einstein's photoelectric equation: Ek=hf−ϕ, the gradient of the graph is h.
Taking the point (10.0×1014,2.65×10−19) and the threshold point (6.0×1014,0):
gradient=ΔfΔEk=(10.0−6.0)×10142.65×10−19−0=4.0×10142.65×10−19
h=6.63×10−34 J s
Marking:
- [1] for identifying that the gradient equals Planck's constant
- [1] for correct calculation of gradient using two points on the line
- [1] for correct answer 6.63×10−34 J s (accept 6.5 to 6.7×10−34)
(c) Determine the work function of the metal in joules. [1]
Answer: ϕ=hf0=6.63×10−34×6.0×1014=3.98×10−19 J
Marking:
- [1] for correct answer 3.98×10−19 J (or using the y-intercept magnitude)
12. An electron is accelerated from rest through a potential difference of 120 V.
(a) Calculate the kinetic energy gained by the electron, in joules. [2]
Answer: Ek=eV=1.60×10−19×120=1.92×10−17 J
Marking:
- [1] for correct formula Ek=eV
- [1] for correct answer 1.92×10−17 J
(b) Calculate the speed of the electron after being accelerated. [2]
Answer: Ek=21mev2
v=me2Ek=9.11×10−312×1.92×10−17=4.215×1013
v=6.49×106 m s−1
Marking:
- [1] for correct substitution into v=2Ek/me
- [1] for correct answer 6.49×106 m s−1 (accept 6.4 to 6.6×106)
(c) Calculate the de Broglie wavelength of this electron. [2]
Answer: λ=mevh=9.11×10−31×6.49×1066.63×10−34=5.913×10−246.63×10−34
λ=1.12×10−10 m=0.112 nm
Marking:
- [1] for correct substitution into de Broglie equation
- [1] for correct answer 1.12×10−10 m
13. Radioactive decay law.
(a) Show that t1/2=λln2. [2]
Answer: At t=t1/2, A=A0/2:
2A0=A0e−λt1/2
21=e−λt1/2
Taking natural logarithm of both sides:
ln(21)=−λt1/2
−ln2=−λt1/2
t1/2=λln2
Marking:
- [1] for substituting A=A0/2 and taking natural logarithm
- [1] for correct algebraic manipulation to obtain t1/2=ln2/λ
(b) Calculate the decay constant λ in s−1. [2]
Answer: t1/2=8.0 days=8.0×24×3600=691200 s
λ=t1/2ln2=6912000.693=1.00×10−6 s−1
Marking:
- [1] for correct conversion of 8.0 days to seconds
- [1] for correct answer 1.00×10−6 s−1
(c) Calculate the initial activity in Bq. [2]
Answer: A0=λN0=1.00×10−6×2.0×1015=2.0×109 Bq
Marking:
- [1] for correct formula A=λN
- [1] for correct answer 2.0×109 Bq
14. Cobalt-60 decay.
(a) Write a nuclear equation for the decay of cobalt-60. [2]
Answer: 2760Co→2860Ni+−10e+νˉe
(or with νˉ as antineutrino)
Marking:
- [1] for correct daughter nucleus 2860Ni (conservation of mass number and charge)
- [1] for correct beta particle −10e and antineutrino
(b) Calculate the half-life of cobalt-60 in years. [3]
Answer: t1/2=λln2=4.17×10−90.693=1.662×108 s
Converting to years:
t1/2=365.25×24×36001.662×108=3.156×1071.662×108=5.27 years
Marking:
- [1] for correct substitution into t1/2=ln2/λ
- [1] for correct answer in seconds (1.66×108 s)
- [1] for correct conversion to years (5.27 years, accept 5.2 to 5.3)
(c) Explain why the activity decreases over time. [1]
Answer: As time passes, the number of undecayed nuclei decreases. Since activity is proportional to the number of undecayed nuclei (A=λN), the activity also decreases.
Marking:
- [1] for linking decreasing number of undecayed nuclei to decreasing activity
15. X-ray diffraction.
(a) State Bragg's law. [1]
Answer: nλ=2dsinθ
where n is the order of diffraction, λ is the wavelength, d is the spacing between crystal planes, and θ is the glancing angle.
Marking:
- [1] for correct equation with all variables defined or clear from context
(b) Calculate the spacing d between the crystal planes. [2]
Answer: For first order, n=1:
d=2sinθnλ=2×sin12.5°1×0.071×10−9=2×0.21647.1×10−11
d=0.43297.1×10−11=1.64×10−10 m=0.164 nm
Marking:
- [1] for correct substitution into Bragg's law
- [1] for correct answer 1.64×10−10 m or 0.164 nm
(c) Explain why X-rays are used rather than visible light. [2]
Answer: The spacing between crystal planes is of the order of 10−10 m. For diffraction to occur, the wavelength must be comparable to the gap spacing. [1] X-rays have wavelengths of the order of 10−10 m, which is comparable to the interplanar spacing, whereas visible light has wavelengths of the order of 10−7 m, which is much too large to produce significant diffraction from crystal planes. [1]
Marking:
- [1] for stating that wavelength must be comparable to the spacing for diffraction
- [1] for comparing X-ray wavelength (∼10−10 m) to visible light wavelength (∼10−7 m)
16. Iron-56 binding energy.
(a) Calculate the mass defect. [2]
Answer: Iron-56 has 26 protons and 30 neutrons.
Total mass of constituent nucleons: mtotal=26×1.0073+30×1.0087=26.1898+30.261=56.4508 u
Mass defect: Δm=56.4508−55.9349=0.5159 u
Marking:
- [1] for correct calculation of total nucleon mass
- [1] for correct mass defect 0.5159 u
(b) Calculate the binding energy in MeV. [2]
Answer: Using 1 u=931.5 MeV/c2:
E=0.5159×931.5=480.6 MeV
Marking:
- [1] for correct conversion factor or using E=Δmc2 with correct unit conversion
- [1] for correct answer 480.6 MeV (accept 479 to 482)
(c) Calculate the binding energy per nucleon. [1]
Answer: AE=56480.6=8.58 MeV per nucleon
Marking:
- [1] for correct answer 8.58 MeV (accept 8.5 to 8.7)
(d) Sketch the binding energy per nucleon curve. [1]
Answer: The graph should show:
- A steep rise from A=0 to a peak near A≈56 (iron-56 region) at about 8.8 MeV per nucleon
- A gradual decline for heavier nuclei, reaching about 7.5 MeV per nucleon at A≈240
- Iron-56 clearly marked at or near the peak
Marking:
- [1] for correct general shape with peak near A=56 and Fe-56 indicated
Teaching notes: Iron-56 has one of the highest binding energies per nucleon, making it the most stable nucleus. This is why fusion releases energy for light nuclei (moving toward the peak) and fission releases energy for heavy nuclei (also moving toward the peak).
17. Laser questions.
(a) Calculate the energy of a single photon. [2]
Answer: E=λhc=632×10−96.63×10−34×3.00×108=6.32×10−71.989×10−25=3.15×10−19 J
Marking:
- [1] for correct substitution
- [1] for correct answer 3.15×10−19 J
(b) Calculate the number of photons emitted per second. [2]
Answer: Power = 2.0 mW=2.0×10−3 J s−1
N=EP=3.15×10−192.0×10−3=6.35×1015 photons per second
Marking:
- [1] for correct method: dividing total power by energy per photon
- [1] for correct answer 6.35×1015 s−1
(c) Explain stimulated emission and why it is essential for laser action. [2]
Answer: Stimulated emission occurs when an incoming photon of the correct energy interacts with an excited atom, causing it to drop to a lower energy level and emit a second photon that is identical to the first (same frequency, phase, direction, and polarisation). [1] This is essential for laser action because it produces coherent, amplified light — each stimulated emission event produces a photon that is in phase with the stimulating photon, leading to a cascade of identical photons that produces the intense, monochromatic, coherent beam characteristic of a laser. [1]
Marking:
- [1] for correct description of stimulated emission
- [1] for explaining that it produces coherent, amplified light essential for laser action
Section C: Data Interpretation and Application (Questions 18–20)
18. Photoelectric experiment with stopping potential data.
(a) Plot a graph of stopping potential Vs against frequency f. [3]
Answer: First convert wavelengths to frequencies using f=c/λ:
| λ / nm | f / ×1014 Hz | Vs / V |
|---|---|---|
| 580 | 5.17 | 0.35 |
| 520 | 5.77 | 0.62 |
| 460 | 6.52 | 0.95 |
| 400 | 7.50 | 1.32 |
| 340 | 8.82 | 1.78 |
Marking:
- [1] for correct calculation of all frequencies
- [1] for correct plotting of all 5 points on the grid
- [1] for best-fit straight line drawn through the points
(b)(i) Determine the threshold frequency. [1]
Answer: The threshold frequency is where the best-fit line intercepts the frequency axis (Vs=0). From extrapolation: f0≈4.5×1014 Hz (accept 4.3 to 4.7×1014 Hz depending on graph accuracy).
Marking:
- [1] for reasonable value read from their graph
(b)(ii) Determine the work function in eV. [1]
Answer: ϕ=hf0=6.63×10−34×4.5×1014=2.98×10−19 J=1.86 eV
(Values will vary depending on the student's graph reading; accept 1.7 to 2.0 eV)
Marking:
- [1] for correct calculation using their threshold frequency value
(c) Explain what the same gradient but higher threshold frequency tells us. [1]
Answer: The gradient of the Vs vs f graph equals h/e, which is a universal constant. The same gradient confirms that Planck's constant is the same for both materials. The higher threshold frequency means the new cathode material has a larger work function (ϕ=hf0), so more energy is required to liberate electrons from its surface.
Marking:
- [1] for stating that the new material has a larger work function
19. Nuclear fusion.
(a) Show that the mass defect is 0.0188 u. [1]
Answer: mbefore=2.0141+3.0160=5.0301 u mafter=4.0026+1.0087=5.0113 u Δm=5.0301−5.0113=0.0188 u✓
Marking:
- [1] for correct calculation showing Δm=0.0188 u
(b) Calculate the energy released in MeV. [2]
Answer: E=0.0188×931.5=17.5 MeV
Marking:
- [1] for correct conversion
- [1] for correct answer 17.5 MeV (accept 17.4 to 17.6)
(c) Calculate the binding energy per nucleon for tritium. [3]
Answer: Tritium (13H) has 1 proton and 2 neutrons.
mnucleons=1×1.0073+2×1.0087=1.0073+2.0174=3.0247 u
Δm=3.0247−3.0160=0.0087 u
E=0.0087×931.5=8.10 MeV
AE=38.10=2.70 MeV per nucleon
Marking:
- [1] for correct calculation of total nucleon mass
- [1] for correct mass defect and binding energy
- [1] for correct binding energy per nucleon 2.70 MeV
(d) Explain why fusion releases energy. [1]
Answer: Fusion releases energy because light nuclei (with low binding energy per nucleon) combine to form a heavier nucleus with a higher binding energy per nucleon. The increase in binding energy per nucleon means the products are more tightly bound, and the excess energy is released.
Marking:
- [1] for correct explanation referencing the binding energy per nucleon curve (moving up the curve toward the peak)
20. Scanning tunnelling microscope.
(a) Explain what is meant by quantum tunnelling. [2]
Answer: Quantum tunnelling is a quantum mechanical phenomenon in which a particle passes through a potential energy barrier that it classically should not be able to surmount, because its kinetic energy is less than the height of the barrier. [1] According to quantum mechanics, the particle has a non-zero probability of being found on the other side of the barrier due to the wave-like nature of matter — the wavefunction does not drop to zero inside the barrier but decays exponentially, so there is a finite probability of the particle emerging on the other side. [1]
Marking:
- [1] for stating that a particle passes through a classically forbidden barrier
- [1] for explaining this in terms of the wave-like nature of matter / non-zero probability
(b) Calculate the ratio of the final current to the initial current. [3]
Answer: IiIf=e−2κdie−2κdf=e−2κ(df−di)
df−di=0.62−0.50=0.12 nm=1.2×10−10 m
IiIf=e−2×1.0×1010×1.2×10−10=e−2.4=0.0907
Marking:
- [1] for correct method: taking the ratio of the two exponential expressions
- [1] for correct calculation of the exponent −2κ(df−di)=−2.4
- [1] for correct answer 0.0907 (or ≈0.091, meaning the current drops to about 9% of its original value)
(c) Explain why the STM can achieve atomic resolution. [2]
Answer: The tunnelling current depends exponentially on the gap width: I∝e−2κd. [1] This means that the current is extremely sensitive to tiny changes in distance — a change of just 0.1 nm changes the current by approximately one order of magnitude. This extreme sensitivity allows the STM to detect individual atoms on a surface, as the tip height changes by atomic-scale amounts when it passes over surface atoms, producing atomic-resolution images. [1]
Marking:
- [1] for referencing the exponential relationship and its extreme sensitivity
- [1] for linking this sensitivity to the ability to detect individual atoms / achieve atomic resolution
Total Marks: 60
Mark Distribution:
| Section | Questions | Marks |
|---|---|---|
| A: Short Answer | 1–10 | 24 |
| B: Structured | 11–17 | 26 |
| C: Data/Application | 18–20 | 10 (part a: 3, b: 2, c: 1) + 7 + 7 = 10 |
| Total | 60 |
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