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A Level H2 Chemistry Acids Bases Salts Quiz
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A-Level Chemistry H2 Quiz - Acids Bases Salts - Answer Key
Section A: Short Answer Questions [15 marks]
1. Complete the following table for gas identification tests. [4 marks]
| Gas | Test and Result |
|---|---|
| Ammonia, NH₃ | Turns damp red litmus paper blue [1] |
| Hydrogen, H₂ | Burns with a pop sound / squeaky pop [1] |
| Chlorine, Cl₂ | Bleaches damp litmus paper (turns white) [1] |
| Sulfur dioxide, SO₂ | Bleaches damp litmus paper but does not rekindle glowing splint [1] |
Marking notes: Accept alternative correct descriptions. Must specify "damp" for litmus tests.
2. Write the ionic equation for the reaction between aluminum oxide and sodium hydroxide solution. [2 marks]
Al₂O₃(s) + 2OH⁻(aq) + 3H₂O(l) → 2[Al(OH)₄]⁻(aq) [2]
Marking notes: Award 1 mark for correct reactants and products, 1 mark for balancing and state symbols.
3. A buffer solution contains 0.15 mol dm⁻³ CH₃COOH and 0.20 mol dm⁻³ CH₃COONa. State the two components that make this an effective buffer system. [2 marks]
Component 1: Weak acid (CH₃COOH) [1] Component 2: Conjugate base / salt of weak acid (CH₃COO⁻ / CH₃COONa) [1]
4. From the following list of reagents, identify which would be suitable for distinguishing between Fe²⁺(aq) and Fe³⁺(aq) ions: [2 marks]
Suitable reagent(s): NaOH(aq) and NH₃(aq) [2]
Marking notes: Both reagents needed for full marks. Fe²⁺ gives green ppt., Fe³⁺ gives brown ppt.
5. Define the term 'amphoteric oxide' and give one example. [2 marks]
Definition: An oxide that reacts with both acids and bases [1] Example: Al₂O₃ / ZnO / PbO [1]
6. State what is observed when aqueous ammonia is added dropwise to copper(II) sulfate solution until in excess. [3 marks]
Initial observation: Blue precipitate forms / Cu(OH)₂ precipitate [1] Final observation: Deep blue solution forms / precipitate dissolves [1] Explanation: Formation of [Cu(NH₃)₄]²⁺ complex ion [1]
Section B: Structured Questions [30 marks]
7. Titration calculation
(a) [2 marks] Working: Exclude titration 1 (rough). Remaining results: 23.85, 23.90, 23.80 cm³ [1] Selected volume: 23.85 cm³ (mean of concordant results) [1]
Marking notes: Accept any reasonable method of selecting concordant results.
(b) [3 marks] HCl + NaOH → NaCl + H₂O Moles HCl = 0.100 × 23.85/1000 = 2.385 × 10⁻³ mol [1] Moles NaOH = 2.385 × 10⁻³ mol (1:1 ratio) [1] Concentration = (2.385 × 10⁻³)/(25.0/1000) = 0.0954 mol dm⁻³ [1]
8. Solubility product calculation
(a) [2 marks] Mr of AgCl = 108 + 35.5 = 143.5 g mol⁻¹ [1] Solubility = (1.43 × 10⁻³)/143.5 = 9.97 × 10⁻⁶ mol dm⁻³ [1]
(b) [3 marks] Equilibrium expression: Ksp = [Ag⁺][Cl⁻] [1] AgCl(s) ⇌ Ag⁺(aq) + Cl⁻(aq), so [Ag⁺] = [Cl⁻] = 9.97 × 10⁻⁶ mol dm⁻³ [1] Ksp = (9.97 × 10⁻⁶)² = 9.94 × 10⁻¹¹ mol² dm⁻⁶ [1]
9. Buffer calculation
(a) [1 mark] CH₃COOH + NaOH → CH₃COONa + H₂O [1]
(b) [2 marks] Moles of CH₃COOH = 0.200 × 50.0/1000 = 0.0100 mol [1] Moles of NaOH = 0.150 × 30.0/1000 = 0.00450 mol [1]
(c) [4 marks] Excess reagent: CH₃COOH [1] After reaction: CH₃COOH remaining = 0.0100 - 0.00450 = 0.00550 mol CH₃COO⁻ formed = 0.00450 mol [1] Total volume = 50.0 + 30.0 = 80.0 cm³ = 0.0800 dm³ [CH₃COOH] = 0.00550/0.0800 = 0.0688 mol dm⁻³ [1] [CH₃COO⁻] = 0.00450/0.0800 = 0.0563 mol dm⁻³ [1]
(d) [3 marks] pH = pKa + log([A⁻]/[HA]) [1] pKa = -log(1.8 × 10⁻⁵) = 4.74 [1] pH = 4.74 + log(0.0563/0.0688) = 4.74 - 0.087 = 4.65 [1]
10. Al³⁺ with NaOH [5 marks]
Initial addition: White precipitate forms [1] Equation: Al³⁺(aq) + 3OH⁻(aq) → Al(OH)₃(s) [1] Excess addition: Precipitate dissolves to form colorless solution [1] Equation: Al(OH)₃(s) + OH⁻(aq) → [Al(OH)₄]⁻(aq) [1] Explanation: Al(OH)₃ is amphoteric, dissolving in excess base to form aluminate ion [1]
11. Magnesium and HCl
(a) [1 mark] Mg(s) + 2HCl(aq) → MgCl₂(aq) + H₂(g) [1]
(b) [3 marks] Moles of Mg = 0.0500/24.3 = 2.06 × 10⁻³ mol [1] Moles of H₂ = 2.06 × 10⁻³ mol (1:1 ratio) [1] Volume of H₂ = 2.06 × 10⁻³ × 24.0 × 1000 = 49.4 cm³ [1]
(c) [2 marks] Factor 1: Increase temperature [1] Factor 2: Increase concentration of HCl / use smaller pieces of Mg / increase surface area [1]
Marking notes: Accept any two valid factors that increase reaction rate.
Total: 45 marks